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Both fundamental and application problems related to the photonic and optoelectronic applications of nanocarbon materials have recently attracted attention of the research community worldwide. The NPO2014 is the fourth workshop in series of meetings devoted to recent advances in this field. The major topics of the Workshop will be the following: Photonics and optoelectronics with graphene and graphene nanoribbons Carbon nanotube photonics and electronics Electronic and optoelectronics of diamond and nanodiamonds Nonlinear optics and spectroscopy of nanocarbon materials Nanocarbon materials synthesis and characterization