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Development of fundamental principles for the synthesis of new monomers and polymers, for the production of ordered organo-hybrid assemblies, based on thiophene and ferrocene derivatives [1]. Interest in such derivatives is due to the fact that thiophene including polythiophene are π-conjugated photo- and electrically conductive compounds, and ferrocene besides the structural features of the molecule, has one of the low oxidation potentials. Moreover, the oxidation of its molecule is not destructive, but is associated only with a change in the valence of the iron entering into its composition, that is, Fe (2+) is oxidized to Fe (3+), which causes specific electrophysical properties. Thus, the photovoltaic, paramagnetic, and nonlinear optical properties of the new thiophene and ferrocene derivatives of llow-molecular compounds and polymers will be studied.