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In this paper we report a state diagram of macromolecules with amphiphilic monomer units depending on the solvent selectivity, surface activity of monomer units and contour length of macromolecule. The diagram of state contains areas of spherical globules, disk-like, toroid and cylindrical structures, regions of vesicle-like, “onion-like” and necklace conformation. We present computer modeling data and results of analytical theory.