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The principally new type of non-catalytic matrix reformers for the conversion of natural gas into nitrogen-free syngas and hydrogen was developed. It was shown that the addition of steam allows stabilizing matrix temperature, decreases the yield of acetylene and makes process more stable. The main advantages of matrix conversion are: auto-thermal and non-catalytic nature of the process which excludes the necessity of introduction of additional heat and deep purification of feed gas; very high specific capacity increasing that of traditional technologies at any rate in 10 times; the possibility to convert without separation and deep pretreatment hydrocarbon gases of practically any origin and composition.