![]() |
ИСТИНА |
Войти в систему Регистрация |
ИПМех РАН |
||
3d and 4d metal ions in the centres of cuboid-shaped polyoxopalladates were studied element-specifically with XAS at low temperatures (4 K) in magnetic fields up to 6 T. Their crystal field parameters and valence states were quantified by comparing XANES, XMCD, and XMLD spectra with CTM4XAS simulations. Their magnetic spin and orbital moments were determined from XMCD spectra using sum rules.