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A new cerium palladium aluminide, CePd2Al8, was synthesized by direct reaction of the elements and its crystal structure was determined from single crystal X-ray diffraction data: sp.gr. C2/m, Z=2, a=11.463(12) Å, b=4.415(4) Å, c=9.126(11) Å, β=123.12(7)˚, Pearson symbol mS22. The final refinement with anisotropic displacement parameters for all the atoms resulted in R(F2)=0.0358 for 900 independent reflections with I>2σ(I) and 36 refined parameters.