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In this work organic surfactant (cetyltrimethylammoniumbromide, CTAB) and pine sawdust (SD) were compared as templates to create advanced textures for oxide catalysts CeZrO2 (CZ) and CuO/CeZrO2 (Сu/CZ) for CO total oxidation. CuO addition (about 25 mol.%) was used to decrease the reaction temperature. The influence of calcination temperature (500 or 600°C) and Ce:Zr ratio on the oxygen mobility and catalytic properties in CO oxidation was studied.