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The scientific interest into FeP, FeAs, CrAs and MnP are largely associated with intrinsic complexity of are unusual magnetic structure, details and generation mechanisms of which are still a matter of discussions. In our recent study, the magnetic structure of a polycrystalline and single crystal FeP was investigated in detail by means of NMR spectroscopy [1,2]. To study an influence of homovalent substitution at non-magnetic (phosphorus) site of the binary helimagnet FeP on its magnetic structure the single-phase polycrystalline sample FeP1-xAsx (x=0.33, 0.50) was synthesized.