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This work describes the synthesis, properties and application of new aliphatic and aromatic derivatives of TTA in various optoelectronic devices. The transformation of TTA in the Friedel-Crafts acylation reaction was studied for the first time . The characteristics of organic field-effect transistors based on them, obtained by both solution and vacuum methods, have been investigated. The influence of dynamic disorder on charge transfer inside annelated organic semiconductors is also discussed.