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Herein we report a general approach to the design and synthesis of new stable supramolecular cluster– porphyrin (CPn) hybrids with 5,15-bis[(p -tolyl)porphyrinato(2-)]ruthenium(carbonyl)(aqua) RuDTolP(CO)H2O and Mo(II) iodide cluster (Bu4N)2[{Mo6I8}(OOC-C5H4N)6] PyMoC. The stepwise formation of discrete kinetically inert CPn(n=1-6) adducts, including geometrical isomers for CP2, CP3, and CP4 species, via Ru-NPy coordination bonds has been observed in solution by 1 H NMR techniques.