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Crystal structure determination was done by X-ray single crystal diffraction analysis diffractometer Xcalibur S with two-dimensional CCD detector, room temperature). It is found that the Ce13Ru2Sn5 intermetallic crystallizes in the tetragonal unit cell and presents a new structural type: I4/mcm (a = b = 22.8999 (2), c = 9.1668 (1) Å, R1 = 0.038 for 2463 independent reflections, 62 variable parameters).