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Influence of nature and the content of zeolite in composition of Pt-catalysts on isomerization and cracking activity in modeling reaction of isomerization of n-hexane and C5-C10 gasoline fraction of Fischer-Tropsch synthesis are investigated. It is shown, that isomerization activity of bifunctional catalysts are determined substantially by zeolite nature, its content in catalyst, temperature of experience and acid properties of zeolites.