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Computational procedures of the land surface biophysical parameters retrieval imply that modeling techniques are available of the outgoing radiation description together with monitoring techniques of remote sensing data processing using registered radiances between the related optical sensors and the land surface objects called “patterns”. Pattern recognition techniques are a valuable approach to the processing of remote sensing data for images of the land surface – atmosphere system. Many simplified codes of the direct and inverse problems of atmospheric optics are considered applicable for the imagery processing of low and middle spatial resolution. Unless the authors are not interested in the accuracy of the final information products, they utilize these standard procedures. The emerging necessity of processing data of high spectral and spatial resolution given by imaging spectrometers puts forward the newly defined pattern recognition techniques. The proposed tools of using different types of classifiers combined with the parameter retrieval procedures for the forested environment are maintained to have much wider applications as compared with the image features and object shapes extraction, which relates to photometry and geometry in pixel-level reflectance representation of the forested land cover. The pixel fraction and reflectance of “end-members” (sunlit forest canopy, sunlit background and shaded background for a particular view and solar illumination angle) are only a part in the listed techniques. It is assumed that each pixel views collections of the individual forest trees and the pixel-level reflectance can thus be computed as a linear mixture of sunlit tree tops, sunlit background (or understory) and shadows. Instead of these photometry and geometry constraints, the improved models are developed of the functional description of outgoing spectral radiation, in which such parameters of the forest canopy like the vegetation biomass density for particular forest species and age are embedded. This permits us to calculate the relationships between the registered radiances and the biomass densities (the direct problem of atmospheric optics). The next stage is to find solutions of this problem as cross-sections of the related curves in the multi-dimensional space given by the parameters of these models (the inverse problem). The typical solutions may not be mathematically unique and the computational procedure is undertaken to their regularization by finding minima of the functional called “the energy for the particular class of forests”. The relevant optimization procedures serve to identify the likelihood between any registered set of data and the theoretical distributions as well as to regularize the solution by employing the derivative functions characterizing the neighborhood of the pixels for the related classes. As a result, we have elaborated a rigorous approach to optimize spectral channels based on searching their most informative sets by combining the channels and finding correlations between them. A successive addition method is used with the calculation of the total probability error. The step up method consists in fixing the level of the probability error that is not improved by further adding the channels in the calculation scheme of the pattern recognition. The best distinguishable classes are recognized at the first stage of this procedure. The analytical technique called “cross-validation” is used at its second stage. This procedure is in removing some data before the classifier training begins employing, for instance, the known “leaving-out-one” strategy. This strategy serves to explain the accuracy category additionally to the standard confusion matrix between the modeling approach and the available ground-based observations, once the employed validation map may not be perfect or needs renewal. Such cross-validation carried out for ensembles of airborne data from the imaging spectrometer produced in Russia enables to conclude that the forest classes on a test area are separated with high accuracy. The proposed approach is recommended to account for the needed set of ground-based measurements during field campaigns for the validation purposes of remote sensing data processing and for the retrieval procedures of such parameters of forests like Net Primary Productivity with an ensured accuracy that results from the described here computational procedures.