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Tetrylenes Based on Polydentate Ligandsдоклад на конференции
- Авторы: Zaitsev Kirill V., Egorov Mikhail P., Churakov Andrei V.
- Международная Конференция (Симпозиум) : The 18th International Symposium on Silicon Chemistry (ISOS-18) in Conjunction with the 6th Asian Silicon Symposium
- Даты проведения конференции: 6-11 августа 2017
- Дата доклада: 8 августа 2017
- Тип доклада: Устный
- Докладчик: Zaitsev Kirill V.
- Место проведения: Ji'nan, China
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Аннотация доклада:
The stabilization of low-valent derivatives of Group 14 elements (M = Si, Ge, Sn, Pb) may be achieved by application of sterically voluminous substituents at M (kinetic stabilization) or by bonding with groups capable to additional donation to the M (thermodynamic stabilization). In this work the synthesis and structure of various polydentate ligands (N,N,N-, N,N,O-, O,N,O-), tetrylenes based on them (germylenes, stannylenes, plumbylenes) and transition metal complexes of the tetrylenes studied are investigated. Approaches to the related silylenes are also described.
- Добавил в систему: Зайцев Кирилл Владимирович