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In this work the first time we systematically studied a series of cationic P(V) phthalocyanines [PcP(OMe)2]+ with different anions: I-, CF3COO-, TsO-, BPh4-, CF3SO3-, HCOO-. All compounds were characterised by set of methods and we succeeded to grow single crystals for each complex. Single crystal XRD (SCXRD) allowed us to determine macrocycle distortion and analyze structural features for the same phosphorus(V) complex with different anions.