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For ceramic precursor powder comprising orthophosphate (Са3(РО4)2), pyrophosphate (Са2Р2О7) and calcium polyphosphate (Са(РО3)2) we used the reaction of calcium propionate with solutions containing pyro- and polyphosphate ions. Powdered precursors for ceramics were synthesized from calcium propionate and various ammonia phosphates. Applying the heat treatment led to the formation of promising biocompatible and bioresorbable ceramic samples.