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The method of amorphous hydrated calcium phosphates synthesis using ion exchange was elaborated. The properties of the suspensions (viscosity, photosensitivity, and critical energy of polymerization) were explored. It was shown that the variation of the photosensitivity of suspensions by changing the colour of powder could sufficiently improve the resolution of stereolithographic printing. Ceramic materials with high osteoconductive properties were obtained using stereolithographic printing. Created porous ceramics based on calcium poly- and pyrophosphated exhibit good resorbability and osteoconductivity and are suitable for medical applications.