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Matrix isolation is a widely used technique for investigations of highly reactive intermediates generated by different ways. In particular, this method is useful for spectroscopic identification of the intermediates occurring in atmospheric chemistry and astrochemistry and laboratory simulation of the mechanisms of relevant processes, which involve reaction of the radiation-induced atoms and radicals. It is worth noting that the behavior of such simple species in rare-gas media is not fully understood so far. The problem of dynamics of impurity atoms and radicals in solids is basically important for chemical physics. Furthermore, the studies in this direction may lead to better understanding of the principles of manipulating the low-temperature chemical reactions, which was the focus of our recent research.