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The stability of amino-containing polymer particles formed by emulsifier-free heterogeneous polymerization of acrylate monomers was studied in terms of the DLVO Theory. In these terms the electrostatic and structural components of potential energy of particles interaction were calculated. It was shown that the incteare in electrostatic component as well as the decrease in structural component of potential energy of interaction in case of particles surface containing hydrophilic amino-groups.