Аннотация:The first conductive single-molecule magnet, (BEDO)4[ReF6]·6H2O [1; BEDO = bis(ethylenedioxo)tetrathiafulvalene], in which conductivity and single-molecule magnetism coexist in the same temperature range was synthesized and characterized structurally. The compound retains its high conductivity down to 4.2 K and displays slow magnetic relaxation.