A MODEL FOR CO INSERTION IN TRANSITION-METAL COMPLEXESстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:A theoretical model recently developed for describing reactions catalysed by transition metal complexes is applied to CO insertion in RML(n) complexes (where M is a transition metal, R is aryl, alkyl, or another sigma-bonded ligand, and L stands for ancillary ligands). The effect of the migrating group R, the metal M, and the number of ancillary ligands L on the insertion step is studied. The mechanism of the double carbonylation reactions of organic halides, catalysed by transition metal complexes, is analysed in the framework of the proposed model.