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FORMATION OF ORGANOPALLADIUM COMPLEXES ON SIO2 AND AL2O3 AS A RESULT OF THE REACTION OF ALLYL ALCOHOL WITH SUPPORTED PDCL2, THERMAL-DECOMPOSITION OF THESE COMPLEXESстатья
Информация о цитировании статьи получена из
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Web of Science
Дата последнего поиска статьи во внешних источниках: 29 ноября 2015 г.
- Авторы: BOGDAN VI, GALICHAYA NN, VASSERBERG VE, ANTOSHIN GV
- Журнал: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
- Том: 41
- Номер: 7
- Год издания: 1992
- Первая страница: 1183
- Последняя страница: 1185
- DOI: 10.1007/BF00864177
- Аннотация: It was established by electronic spectroscopy in the UV and visible regions and mass spectrometry that when allyl alcohol reacts from the gas phase with palladium chloride supported on SiO2 and Al2O3 a complex similar in characteristics to a bis-pi-allylpalladium chloride complex that is fixed on the surface of the support is formed. Decomposition of this complex in vacuo occurs at 135-degrees-C with the formation of allyl chloride and zero-valence supported palladium.
- Добавил в систему: Богдан Виктор Игнатьевич