Role of macrocyclic effect in complex formation of palladium(II) with ligands anchored on a solid supportстатья
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Дата последнего поиска статьи во внешних источниках: 6 декабря 2018 г.
Аннотация:The method for grafting dithiacrown ether and its linear analogue to the silica surface using
preliminary prepared organosilicon derivative is developed. The importance of the acylation
step in the process of grafting is underlined. The acylation is required to prevent sorption of
platinum metals complex anions by the anion exchange mechanism, the probability of which
increases due to protonation of the spacer in an acidic medium. The interaction of palladium(II) with anchored ligands in hydrochloric acid media was studied in details. The comparative study of two sorbents revealed that the macrocyclic eff ect plays a negligible role in binding of palladium(II) ions. Therefore, linear ligands are preferred for the development of sorbents for molecular recognition of platinum metals ions.