Tridecanuclear CuII11Na2 cagelike silsesquioxanes

Авторы: Astakhov Grigorii S., Bilyachenko Alexey N., Levitsky Mikhail M., Korlyukov Alexander A., Zubavichus Yan V., Dorovatovskii Pavel V., Khrustalev Victor N., Vologzhanina Anna V., Shubina Elena S.
Журнал: Crystal Growth and Design
Том: 18
Номер: 9
Год издания: 2018
Издательство: American Chemical Society
Местоположение издательства: United States
Первая страница: 5377
Последняя страница: 5384
DOI: 10.1021/acs.cgd.8b00778
Аннотация: A series of three unprecedented heterometallic copper(II) sodium silsesquioxanes were isolated (i) via the unusual rearrangement process during synthesis of coordination polymers or (ii) via the self-assembly reaction using 2,2′-bipyridine. The unique type of these products’ molecular topology consists of an unusual fusion of two sandwich-like components (each including five copper and one sodium sites) via a central copper ion. These compounds correspond to the highest nuclearity among Cu(II)-based cage silsesquioxanes reported to date.
Добавил в систему: Левицкий Михаил Моисеевич

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