Electrocatalytic dehalogenation of alpha-bromoketones in the presence of Cp2TiCl2статья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:Processes of direct and electrocatalytic (in the presence of electrochemically reduced Cp2TiCl2) reduction of three alpha-bromoketones containing the C(sp(3))-Br or C(sp(2))-Br bond, viz., 2-bromo-and 2,6-dibromo-4,4-dimethylcyclohexa-2,5-dien-1-ones and alpha-bromo-acetophenone, were studied by cyclic voltammetry and preparative electrolysis. In all cases, the dissociative electron transfer proceeds via the concerted mechanism. Preparative electrolysis of these alpha-bromoketones in the presence of Cp2TiCl2 affords the reductive debromination products in 40-80% yield at low cathodic potentials (-0.85 V vs. Ag/AgCl/KCl). In the case of 2,6-dibromo-4,4-dimethylcyclohexa-2,5-dien-1-one in the potentiostatic regime, only one bromine atom can be eliminated selectively.