THEORY OF EQUILIBRIUM AND KINETIC PHENOMENA IN ELECTRON-CONDUCTING POLYMERSстатья
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Дата последнего поиска статьи во внешних источниках: 29 мая 2015 г.
Аннотация:Theoretical analysis of distributions of electric potential and concentrations of electronic and ionic species across metal/polymer/solution system has shown existence of insulating (at very low charging degrees) and conductive states of the film. In the latter case the ratio of cations and anions in the film is a function of the doping degree and bulk electrolyte concentration as well as of ionic solvation properties of the film. Phenomena within the strong coion expulsion regime have been analyzed, including quasiequilibrium charging curves (at various compositions of electronic species in the film), reaction kinetics at polymer/solution interface, low-amplitude impedance.