Synthesis of Sulfonamide Derivatives of Carboranyl Porphyrins Based on 5-(4-Aminophenyl)-10,15,20-triphenylporphyrin and Mercapto Carboranesстатья
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Статья опубликована в журнале из перечня ВАК
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 21 февраля 2019 г.
Аннотация:New carboranyl substituted sulfonamide porphyrins were synthesized in good yields by the reaction of amino group
of 5-(p-aminophenyl)-10,15,20-triphenylporphyrin with carboranylsulfonyl chlorides prepared in situ by oxidative
chlorination of corresponding mercapto carborane with trichloroisocyanuric acid in MeCN–H2
O system. The reactions
were carried out under mild conditions. The structure of all compounds obtained was confirmed by means of electronic,
IR, 1
Н and 11B NMR spectroscopy and mass spectrometry. Quantum-chemical studies by DFT calculations were carried
out for synthesized porphyrin derivatives.