|
ИСТИНА |
Войти в систему Регистрация |
ИПМех РАН |
||
ANALYSIS OF SKELETAL REARRANGEMENT ROUTES IN THE TRICYCLO[4.2.2.0(2,5)]DECANE SYSTEM IN THE COURSE OF ELECTROPHILIC ADDITION-REACTIONSстатья
Информация о цитировании статьи получена из
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 29 мая 2015 г.
- Авторы: KOZMIN A.S., POTEKHIN K.A., SHCHERBUKHIN V.V., ZEFIROV N.S., STRUCHKOV Y.T.
- Журнал: New Journal of Chemistry
- Том: 18
- Номер: 6
- Год издания: 1994
- Издательство: Royal Society of Chemistry
- Местоположение издательства: United Kingdom
- Первая страница: 675
- Последняя страница: 686
- Аннотация: Addition of electrophilic reagents to derivatives of tricyclo[4.2.2.0.(2,5)]deca-3,7-diene (1a-e) and tricyclo[4.2.2.0(2,5)]deca-3,7,9-triene (2) yields compounds with several new types of carbon skeleton. Detailed comparison of X-ray data for the reaction products revealed a variety of geometrical anomalies in their molecular structure, indicating that it may be subject to skeletal rearrangements. Reasonable multistep mechanisms for these rearrangements were suggested for the initial olefins by our ICAR computer program; the probability of these mechanisms was estimated by molecular mechanics calculations. This analysis suggests explanations for the predominant formation of major reaction products and for different rearrangement paths of the similar compounds 1 and 2.
- Добавил в систему: Зефиров Николай Серафимович