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Reactivity of perfluorinated O-anionsстатья
- Авторы: Grinevskaja, V K., Del'tsova D.P., Gervits L.L.
- Журнал: Fluorine notes (Фторные заметки)
- Том: 63
- Год издания: 2009
- Первая страница: No pp. given.
- Последняя страница: No pp. given.
- Аннотация: The reaction of perfluoro-N-methylmorpholine with SbF5 leads to perfluoromorpholinimine [2,2,3,3,5,6,6-heptafluoro-3,6-dihydro-2H-1,4-Oxazine (I)] in good yield. Perfluoromorpholinimine (I) also reacts with alkali metal fluorides (CsF) in aprotic solvents to give the corresponding stable perfluorinated aza- anion (II) (according to 19F NMR data). We have studied the reactivity of aza-anion (II) in its reactions with various agents.
- Добавил в систему: Гервиц Лев Львович