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The kinetics of living free-radical polymerization of styrene in the presence of alkoxyamine: Interpretation within the framework of secondary inhibition hypothesisстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 26 декабря 2018 г.
- Авторы: Kurochkin S.A., Grachev V.P., Korolev G.V.
- Журнал: Polymer Science, Series A
- Том: 49
- Номер: 4
- Год издания: 2007
- Издательство: Pleiades Publishing, Ltd
- Местоположение издательства: Road Town, United Kingdom
- Первая страница: 373
- Последняя страница: 380
- DOI: 10.1134/S0965545X07040025
- Аннотация: The kinetics of the free-radical polymerization of styrene at 120 degrees C in the presence of alkoxyamine as a living polymerization agent has been studied. The alkoxyamine forms in situ with a 100-fold variation in the initial concentration of 2,2,6,6-tetramethyl-1-piperidinyloxy. The rate of the process at the stationary stage decreases with an increase in the initial concentration of 2,2,6,6-tetramethyl-1-piperidinyloxy. The computer simulation of the kinetic features of the process under study demonstrates that this tendency is related to the possible secondary inhibition of the process by alkoxyamine and/or hydroxylamine arising in the system in the course of polymerization.
- Добавил в систему: Курочкин Сергей Александрович