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Adsorption of metalloarene cations at the aqueous solution/mercury and solution/air interfaceстатья
Информация о цитировании статьи получена из
Scopus,
Web of Science
Дата последнего поиска статьи во внешних источниках: 12 октября 2013 г.
- Авторы: Gerovich V.M., Podgornaya M.I., Damaskin B.B.
- Журнал: SOVIET ELECTROCHEMISTRY
- Том: 21
- Номер: 10
- Год издания: 1985
- Первая страница: 1262
- Последняя страница: 1266
- Аннотация: The adsorption of the metalloarene cations, bis(benzene)chromium and bis(biphenyl)chromium, was studied in the presence of sulfate and iodide as the anions at the solution/mercury interface by measuring electrocapillary curves, and at the solution/air interface by measuring the maximum pressure in air bubbles. Adsorbability of the metalloarene cations on mercury was found to arise as a result of complex combination of a number of factors: their positive charge, the expulsion effect, the pi -electron effect, the presence of an unpaired electron, and also the influence of the base-electrolyte anions.
- Добавил в систему: Борзенко Марина Игоревна