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Electrical double layer structure in surface-inactive electrolytes on a liquid Cd-Ga electrode in methanol and propylene carbonateстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Emets V.V., Damaskin B.B., Bagotskaya I.A.
- Журнал: Russian Journal of Electrochemistry
- Том: 37
- Номер: 1
- Год издания: 2001
- Издательство: Maik Nauka/Interperiodica Publishing
- Местоположение издательства: Russian Federation
- Первая страница: 88
- Последняя страница: 94
- DOI: 10.1023/A:1009087914316
- Аннотация: Differential capacitance curves and potentials of zero charge are obtained for liquid Cd-Ga electrodes in methanol and propylene carbonate solutions of a surface-inactive electrolyte. It is found that double-layer characteristics of the Cd-Ga electrode differ from those of a Ga electrode both in nonaqueous solutions and in water. The lyophilic nature of the Cd-Ga electrode, relative to methanol and propylene carbonate, is shown to approach that of the In-Ga electrode. In the absence of a metal-solvent chemisorption interaction, the difference between reciprocal "metallic" capacitances for Cd-Ga and Hg electrodes is independent of the solvent nature. The chemisorption interaction between the solvents and Cd-Ga, Ga, and In-Ga electrodes increases with the solvents' donor number.
- Добавил в систему: Дамаскин Борис Борисович