Comparison of the ionic adsorption theories for the electrode/solution interface by computer simulationстатья
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Дата последнего поиска статьи во внешних источниках: 29 мая 2015 г.
Авторы:
Damaskin B. ,
Pankratova I. ,
Palm U. ,
Anni K. ,
Väärtnǒu M. ,
Salve M.
Журнал:
Journal of Electroanalytical Chemistry
Том:
234
Номер:
1-2
Год издания:
1987
Издательство:
Elsevier Sequoia
Местоположение издательства:
Switzerland
Первая страница:
31
Последняя страница:
53
DOI:
10.1016/0022-0728(87)80160-2
Аннотация:
A computer simulation method for the analysis of the ionic adsorption in mixed electrolyte systems with constant ionic strength has been elaborated. It has been shown that the effects due to counter ion coadsorption in the inner layer and to the competitive adsorption of the reference ions, can distort significantly the specific adsorption values obtained by the sensitive calculation methods excluding numerical differentiation. Peculiarities of contemporary double-layer models (the Grahame-Parsons, Alekseev-Popov-Kolotyrkin and Vorotyntsev theories) have been revealed by analysis of a number of different model systems with known true specific adsorption values assuming an independence of the inner-layer capacity on specific adsorption. Criteria for the identity and applicability limits of the models considered have been established. © 1987.
Добавил в систему:
Дамаскин Борис Борисович