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The influence of crystallographic inhomogeneity of a polycrystalline electrode surface on the behavior of the electric double-layerстатья
Информация о цитировании статьи получена из
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 29 мая 2015 г.
- Авторы: Bagotskaya I.A., Damaskin B.B., Levi M.D.
- Журнал: Journal of Electroanalytical Chemistry
- Том: 115
- Номер: 2
- Год издания: 1980
- Издательство: Elsevier Sequoia
- Местоположение издательства: Switzerland
- Первая страница: 189
- Последняя страница: 209
- DOI: 10.1016/S0022-0728(80)80325-1
- Аннотация: The specific features of the electric double-layer structure at polycrystalline electrodes in the absence of specific ion adsorption have been examined for two different models: Model I and Model II. In the case of Model I each of the faces showing on the surface of a polycrystalline electrode retains its own Helmholtz and diffuse double layers. In the case of Model II the faces retain only their own Helmholtz layer, whereas the diffuse layer is common to the entire electrode surface. The difference of zero charge potentials of the faces is defined both by their dissimilar hydrophilic properties and by different work functions. The experimental data available at present on the electric double-layer structure at polycrystalline electrodes for which the potentials of zero charge of the faces differ significantly are described by Model I. © 1980
- Добавил в систему: Дамаскин Борис Борисович