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Comparison of isotherms for specific adsorption of ions from constant ionic-strength solutionsстатья
Информация о цитировании статьи получена из
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Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 27 мая 2015 г.
- Авторы: Damaskin B., Palm U., Petyarv E., Salve M.
- Журнал: Journal of Electroanalytical Chemistry
- Том: 51
- Номер: 1
- Год издания: 1974
- Издательство: Elsevier Sequoia
- Местоположение издательства: Switzerland
- Первая страница: 179
- Последняя страница: 189
- DOI: 10.1016/0368-1874(74)87016-4
- Аннотация: It has been shown that the specific adsorption of caesium ions from the constant ionic strength system can be described at the bismuth-aqueous solution interface by the virial isotherm, including the concentration of surface-active ions at the outer Helmholtz plane as a concentration variable; at the same time the specific adsorption of counter-ions must be excluded. Comparison of the main characteristics of adsorption isotherms applicable to description of specific adsorption of cations at the bismuth electrode has been made. An estimate of the accuracy of calculation of the charge of specifically adsorbed ions has been made by means of the potential shift due to adsorption of surface-active ions at constant electrode charge. © 1974.
- Добавил в систему: Дамаскин Борис Борисович