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Crystal chemistry of KCuMn3(VO4)3 in the context of detailed systematics of the alluaudite familyстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 26 сентября 2016 г.
- Авторы: Yakubovich O.V., Kiryukhina G.V., Dimitrova O.V.
- Журнал: Crystallography Reports
- Том: 61
- Номер: 4
- Год издания: 2016
- Издательство: Maik Nauka/Interperiodica Publishing
- Местоположение издательства: Russian Federation
- Первая страница: 566
- Последняя страница: 575
- DOI: 10.1134/S1063774516040246
- Аннотация: The crystal structure of new manganese potassium copper vanadate KCuMn3(VO4)3, which was prepared by the hydrothermal synthesis in the K2CO3–CuO–MnCl2–V2O5–H2O system, was studied by X-ray diffraction (R = 0.0355): a = 12.396(1) Å, b = 12.944(1) Å, c = 6.9786(5) Å, β = 112.723(1)grad, sp.gr.C2/c, Z = 4, ρcalc = 3.938 g/cm3. A comparative analysis of the crystal chemical features of the new representative of the alluaudite family and related structures of minerals and synthetic phosphates, arsenates, and vanadates of the general formula A(1)A(1)'A(1)''A(2)A(2)'M(1)M(2)2(TO4)3(where A are sites in the channels trahedra) was performed. A classification of these ding to the occupancy of A sites is suggested.
- Добавил в систему: Якубович Ольга Всеволодовна