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The influence of zeolite morphology on the conversion of methane to methanol on copper-exchanged omega zeolite (MAZ)статья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 1 августа 2019 г.
- Авторы: Knorpp Amy J., Newton Mark A., Sushkevich Vitaly L., Zimmermann Patrik P., Pinar Ana B., van Bokhoven Jeroen A.
- Журнал: Catalysis Science & Technology
- Том: 9
- Номер: 11
- Год издания: 2019
- Первая страница: 2806
- Последняя страница: 2811
- DOI: 10.1039/C9CY00013E
- Аннотация: Methane is often flared due to the heavy economic burden of transportation, particularly at rural petroleum extraction sites. Directly converting methane to methanol is possible through a stepwise process with copper-exchanged zeolites. Factors affecting this conversion are not yet fully understood. Omega zeolite (MAZ) can yield 197 μmol per gram-zeolite, the highest reported thus far. Here we show that the synthesis and resulting morphology of the zeolite play an enormous role in the yield of methanol. High yields are only achieved when the zeolite has a longer stick-like bundled morphology (2–4 μm by 100 nm). When the zeolite forms small spherulitic aggregates, the methanol yield is severely diminished (60–97 μmol-methanol per gram-zeolite). This difference originates from minute changes in the synthesis procedure, emphasizing the extreme sensitivity of zeolite properties towards synthesis conditions. This work shows that selecting a parent zeolite is crucial and is an opportunity for process optimization to achieve high and industrially-relevant methanol yields.
- Добавил в систему: Сушкевич Виталий Леонидович