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Aromaticity Suppression by Intermolecular Coordination. Optical Spectra and Electronic Structure of Heavy Carbene Analogues with an Amidophenolate Backboneстатья
Статья опубликована в высокорейтинговом журнале
Статья опубликована в журнале из списка Web of Science и/или Scopus- Авторы: Aysin R.R., Bukalov S.S., Leites L.A., Lalov A.V., Tsys K.V., Piskunov A.V.
- Журнал: Organometallics
- Год издания: 2019
- Издательство: American Chemical Society
- Местоположение издательства: United States
- DOI: 10.1021/acs.organomet.9b00434
- Аннотация: Experimental optical (UV−vis, Raman) and computational magnetic (NICS, GIMIC) criteria were used to study the aromaticity of group 14 N,O-heterocyclic carbenes tBuAPE (AP = amidophenolate, E = Ge, Sn, Pb). The UV−vis and Raman spectra of the monomeric compound with E = Ge were shown to differ significantly from those of dimeric compounds with E = Sn, Pb. The reason for these phenomena is suppression in the dimeric molecules of 10π aromaticity due to partial filling of the vacant pz orbital of the EII atom caused by intermolecular coordination N→ EII. The monomeric forms of all molecules studied are aromatic according to all the criteria used
- Добавил в систему: Айсин Ринат Равильевич
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