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Stabilized Germylenes Based on Diethylenetriamines and Related Diamines: Synthesis, Structures, and Chemical Propertiesстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Scopus,
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Huang Mengmeng, Kireenko Marina M., Zaitsev Kirill V., Oprunenko Yuri F., Churakov Andrei V., Howard Judith A.K., Lermontova Elmira Kh, Sorokin Denis, Linder Thomas, Sundermeyer Joerg, Karlov Sergey S., Zaitseva Galina S.
- Журнал: European Journal of Inorganic Chemistry
- Номер: 23
- Год издания: 2012
- Издательство: John Wiley & Sons Ltd.
- Местоположение издательства: United Kingdom
- Первая страница: 3712
- Последняя страница: 3724
- DOI: 10.1002/ejic.201200363
- Аннотация: A series of novel, low-valent germanium compounds 2a-2j based on four diethylenetriamines 1a-1d, (methyl)bis(pyrrol-2-ylmethyl)amine (1e), N,N'-(sulfanediyldibenzene-2,1-diyl)bis(pentafluoroaniline) (1f), N,N'-(oxydibenzene-2,1-diyl)bis(pentafluoroaniline) (1g), and (pentafluorophenyl)amines 1i and 1j have been obtained either by the reaction of Ge[N(SiMe3)2]2 with various diamines (1a-1e) or by the metathesis reaction of [GeCl2 center dot dioxane] with lithium amides. The oxidative insertion (with halogenation reagents, MeI, disulfides), [1+4] cycloaddition, and oxidation reactions of the synthesized germylenes were investigated. The compositions and structures of the novel compounds were established by elemental analysis, 1H and 13C NMR spectroscopy, and X-ray diffraction analysis (germylenes 2b, 2i, 2j, Ge4+ compounds 5b, 7a, 7b, 8, 10, 11). All the synthesized germylenes are monomeric.
- Добавил в систему: Опруненко Юрий Федорович