Secondary nucleation in the formation of methane crystal hydrateстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Авторы:
Makogon Yu F. ,
Melikhov I.V. ,
Kozlovskaya E.D. ,
Bozhevol’Nov V.E.
Журнал:
Russian Journal of Physical Chemistry A
Том:
81
Номер:
10
Год издания:
2007
Издательство:
Pleiades Publishing, Ltd
Местоположение издательства:
Road Town, United Kingdom
Первая страница:
1645
Последняя страница:
1649
DOI:
10.1134/S0036024407100184
Аннотация:
The kinetic data on crystallization and a morphological analysis of a layer of CH4 • 6H2O hydrate crystals formed on the surface of water as a result of methane absorption showed that secondary nucleation occurred during hydrate crystallization. The mutual arrangement of crystals in the layer revealed photographically in situ was evidence that part of nuclei produced on the surface of previously formed crystals went away from the surface into solution and grew there independently of "mother" crystals, although the probability of such transfer into an immobile solution remained low. In view of this, a model of crystal growth generating secondary crystals was developed. © 2007 Pleiades Publishing, Ltd.
Добавил в систему:
Мелихов Игорь Витальевич