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Potential of ethylenediaminedi(o-hydroxyphenylacetic acid) and N,N’- bis(hydroxybenzyl)ethylenediamine-N,N’-diacetic acid for the determination of metal ions by capillary electrophoresisстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
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Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Krokhin O.V., Kuzina O.V., Hoshino H., Shpigun O.A., Yotsuyanagi T.
- Журнал: Journal of Chromatography A
- Том: 890
- Номер: 2
- Год издания: 2000
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Первая страница: 363
- Последняя страница: 369
- DOI: 10.1016/S0021-9673(00)00554-9
- Аннотация: Two aromatic polyaminocarboxylate ligands, ethylenediaminedi(o- hydroxyphenylacetic acid) (EDDHA) and N,N’-bis(hydroxybenzyl)ethylenediamine- N,N’-diacetic acid (HBED), were applied for the separation of transition and heavy metal ions by the ion-exchange variant of electrokinetic chromatography. EDDHA structure contains two chiral carbon centers. It makes it impossible to use the commercially available ligand. All the studied metal ions showed two peaks, which correspond to meso and rac forms of the ligand. The separation of metal-HBED chelates was performed using poly(diallyldimethylammonium) polycations in mixed acetate-hydroxide form. Simultaneous separation of nine single- and nine double-charged HBED chelates, including In(III), Ga(III), Co(II)-(III) and Mn(II)-(III) pairs demonstrated the efficiency of 40 000-400 000 theoretical plates. The separation of Co(III), Fe(III) complexes with different arrangements of donor groups and oxidation of Co(II), Mn(II), Fe(II) ions in reaction with HBED have been discussed. (C) 2000 Elsevier Science B.V.
- Добавил в систему: Шпигун Олег Алексеевич