|
ИСТИНА |
Войти в систему Регистрация |
ИПМех РАН |
||
SYNTHESIS OF 4-METHOXYBIPHENYL USING PD-CONTAINING CATALYSTS BASED ON POLYMERIC MATRIX OF FUNCTIONALIZED HYPERCROSSLINKED POLYSTYRENEстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 13 ноября 2019 г.
- Авторы: Nikoshvili L., Bykov A., Sidorov A., Matveeva V., Tyamina I., Sulman M., Sulman E., Nemygina N., Stein B.
- Журнал: BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS
- Том: 10
- Номер: 3
- Год издания: 2015
- Первая страница: 256
- Последняя страница: 265
- DOI: 10.9767/bcrec.10.3.8805.256-265
- Аннотация: his paper describes synthesis of Pd-containing catalysts of Suzuki cross-coupling based on amino-functionalized hypercrosslinked polystyrene. The investigation of the influence of a palladium concentration, solvent composition, temperature, type and concentration of base, and a type of a gas phase was carried out. It was shown that the catalyst developed allows achieving conversion of 4-bromoanisole higher than 98% for less than 1 h at mild reaction conditions and in the absence of a phase transfer agent. Catalyst reduction was found to result in formation of small Pd nanoparticles (about 3 nm in diameter) and a large number of Pd clusters, which are highly active in Suzuki-Miyaura cross-coupling (conversion of 4-bromoanisole reached 90.2% for 3 h).
- Добавил в систему: Сульман Михаил Геннадьевич