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Br-81/Br-79-induced C-13 isotope shifts and line broadening in the C-13 NMR spectrum of methyl bromideстатья
Информация о цитировании статьи получена из
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Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Raynes W.T., Sergeyev N.M., Sandor P., Grayson M.
- Журнал: Magnetic Resonance in Chemistry
- Том: 35
- Номер: 2
- Год издания: 1997
- Издательство: John Wiley & Sons Inc.
- Местоположение издательства: United States
- Первая страница: 141
- Последняя страница: 143
- DOI: 10.1002/(SICI)1097-458X(199702)35:2<141::AID-OMR52>3.3.CO;2-S
- Аннотация: NMR studies of the C-13 isotope shift between (CH3Br)-Br-79 and (CH3Br)-Br-81 and of the linewidths of the two resolved resonances were carried out as part of a wider study of the NMR properties of methyl halide molecules. The isotope shift of 1.12 ppb can be readily accounted for in terms of the very slight shortening of the C-Br bond (0.000 008 Angstrom) which occurs upon replacing Br-79 by Br-81. From the isotope shift it is shown that the C-Br bond length derivative of the carbon-13 shielding is -140 ppm Angstrom(-1). There is no need to involve the change in bromine nuclear quadrupole moment to explain the isotope shift, The linewidths are influenced by scaler relaxation of the second kind and, from the observed values of 0.084 and 0.100 Hz for (CH3Br)-Br-79 and (CH3Br)-Br-81, respectively, it is possible to deduce that J(C-13 Br-79) = 48 Hz and J(C-13 Br-81) is, 45 Hz. These results are in accordance with extrapolation from previously measured results for CBr4, CHBr3 and CH2Br2. (C) 1997 by John Wiley & Sons, Ltd.
- Добавил в систему: Сергеев Николай Михайлович