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Effect of electronic structure of methylphenols on acidity in the ground and electron-excited stateстатья
Информация о цитировании статьи получена из
Scopus,
Web of Science
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Abronin I.A., Gagarin S.G., Zhidomirov G.M.
- Журнал: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
- Том: 23
- Номер: 11
- Год издания: 1975
- Первая страница: 2537
- Последняя страница: 2538
- DOI: 10.1007/BF00922153
- Аннотация: 1. The effect of methyl groups on the acidity of methylphenols in the ground and first electron-excited states obeys the additivity rule. The increments for the corresponding relations were found. 2. The greatest contribution to a change in the pK in the ground state are made by the o- and p-CH 3 groups, which, in harmony with the distribution of the electron density, is explained by the resonance effect of the methyl group. The effect of the m-CH 3 groups becomes predominant in the first excited state. © 1975 Plenum Publishing Corporation.
- Добавил в систему: Жидомиров Георгий Михайлович