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Cellulose Conversion Into Hexitols and Glycols in Water: Recent Advances in Catalyst Development Olegстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 6 февраля 2020 г.
- Авторы: Manaenkov Oleg V., Kislitsa Olga V., Matveeva Valentina G., Sulman Ester M., Sulman Mikhail G., Bronstein Lyudmila M.
- Журнал: Frontiers in Chemistry
- Том: 7
- Год издания: 2019
- Первая страница: 1
- Последняя страница: 8
- DOI: 10.3389/fchem.2019.00834
- Аннотация: Conversion of biomass cellulose to value-added chemicals and fuels is one of the most important advances of green chemistry stimulated by needs of industry. Here we discuss modern trends in the development of catalysts for two processes of cellulose conversion: (i) hydrolytic hydrogenation with the formation of hexitols and (ii) hydrogenolysis, leading to glycols. The promising strategies include the use of subcritical water which facilitates hydrolysis, bifunctional catalysts which catalyze not only hydrogenation, but also hydrolysis, retro-aldol condensation, and isomerization, and pretreatment (milling) of cellulose together with catalysts to allow an intimate contact between the reaction components. An important development is the replacement of noble metals in the catalysts with earth-abundant metals, bringing down the catalyst costs, and improving the environmental impact.
- Добавил в систему: Сульман Михаил Геннадьевич