Dielectric relaxation in Bi2Ti2O7 single crystalsстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 6 февраля 2020 г.
Аннотация:Large impurity-free Bi2Ti2O7 single crystals were grown by slow cooling
of a melt. Their crystal structure and dielectric properties as a function
of temperature at different frequencies were studied for the first time.
A step-like frequency-dependent anomaly was observed at a temperature
of about 220 K at a frequency of 1 kHz. The relaxation behavior is
well described by the empirical Vogel-Fulcher relation typical for
relaxor ferroelectrics. Based on the value of fitting parameters, Bi2Ti2O7
occupies an intermediate position between the canonical relaxor
PbMg1/3Nb2/3O3 on the one hand and lead-free relaxors based on
BaTiO3 on the other hand. The possible mechanisms of the observed
dielectric relaxation of the Bi2Ti2O7 single crystals are discussed.