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Полный текст
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The kinetics of free-radical nonbranched-chain processes of addition to unsaturated compounds (such as alkenes, formaldehyde, dioxygen) was investigated. The proposed schemes include the reaction competing with chain propagation reactions through a reactive free radical. The chain evolution stage in these schemes involves three or four types of free radicals. One of them – СН2=С(СН3)ĊН2, СН2=СНĊНОН, НĊ=O, o-СН3С6Н4СН2O4•, or HO4• – is relatively low-reactive and inhibits the chain process by shortening of the kinetic chain length. The energetics of the key radical-molecule reactions is considered. |
M.M._Silaev_IJSRCH_2020_51_6-36_website.pdf |
917,4 КБ |
19 марта 2020
[SilaevMM]
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