A polymer in an ionic liquid: Structural properties of a system during attraction between the polymer and cations of the ionic liquidстатья
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Дата последнего поиска статьи во внешних источниках: 24 октября 2016 г.
Авторы:
Zherenkova L.V. ,
Komarov P.V. ,
Pavlov A.S.
Журнал:
Polymer Science, Series A
Том:
52
Номер:
8
Год издания:
2010
Издательство:
Pleiades Publishing, Ltd
Местоположение издательства:
Road Town, United Kingdom
Первая страница:
864
Последняя страница:
871
DOI:
10.1134/S0965545X10080146
Аннотация:
In terms of the polymer integral equation theory, structuring in ionic liquids containing flexiblechain polymers under the conditions of good solubility is studied for the first time. The influence of the polymer concentration on the structural properties of system components is studied at different lengths of polymer molecules. The structural organization of the ionic liquids is shown to be fairly stable after addition of the polymer. When there is attraction between the polar groups of cations of the ionic liquid and polymer molecules, the calculated structural factors suggest intermediate-range scales of polymer-component ordering. Given this, for any considered length of polymer molecules, there is a range of polymer concentrations in which the characteristic scale of ordering decreases with an increase in polymer density according to a power law. © 2010 Pleiades Publishing, Ltd.
Добавил в систему:
Комаров Павел Вячеславович