2D-Metal-organic coordination polymers of lanthanides (La(III), Pr(III) and Nd(III)) with redox-active dioxolene bridging ligandстатья
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Авторы:
Kharitonov Alexandr,
Trofimova Olesya Yur\textquotesingleevna,
Meshcheryakova Irina N.,
Fukin Georgii K.,
Khrizanforov Mikhail,
Budnikova Yulia H.,
Bogomyakov Artem Stepanovich,
Aysin Rinat R.,
Kovalenko Konstantin A.,
Piskunov Alexandr Vladimirovich
Аннотация:Synthesis, crystal structure, thermal stability, porosity and magnetic properties of three new layered coordination polymers [(M2(pQ)3)·4DMAA]n (M3+ = La3+ (1), Pr3+ (2), Nd3+ (3); pQ2- - dianionic form of 2,5-di-hydroxy-3,6-di-tert-butyl-para-quinone; DMAA = N,N’-dimethylacetamide) are reported. Coordination polymers obtained were investigated by solid-state electrochemistry which demonstrates multistep one-electron transformations caused by the presence of redox-active dioxolene ligands.