First Radical Cation Salts Based on Dibenzotetrathiafulvalene (DBTTF) with Metallacarborane Anions: Synthesis, Structure, Propertiesстатья
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Дата последнего поиска статьи во внешних источниках: 13 января 2021 г.
Аннотация:The new radical cation salts based on transition metal bis(dicarbollides) with dibenzotetrathiafulvalene (DBTTF) donors (DBTTF)[3,3’-Fe(1,2-C2B9H11)2] (1) and (DBTTF)2[3,3’-Cr(1,2-C2B9H11)2] (2) were synthesized and their crystal structures were determined by single crystal X-ray diffractions. The electric conductivity measurements revealed that these compounds are semiconductors at room temperature and the conductivity of (DBTTF)2[3,3’-Cr(1,2-C2B9H11)2] is ∼500 times higher than that of its BEDT-TTF analogue.